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vanadyl acetylacetonate : ウィキペディア英語版
vanadyl acetylacetonate

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Vanadyl acetylacetonate is the chemical compound with the formula VO(C5H7O2)2. This blue-green coordination complex consists of the vanadyl group, VO2+, bound to two acetylacetonate anions, acac. Like other charge-neutral acetylacetonates, this complex is soluble in organic solvents.
==Synthesis==
The complex is prepared from vanadium(IV), e.g. vanadyl sulfate, or vanadium(V) precursors, such as vanadium pentoxide. The equation for the redox reaction starting from the pentoxide can be described by this approximate equation:
:2 V2O5 + 9 C5H8O2 → 4 VO(C5H7O2)2 + (CH3CO)2CO + 5 H2O
The compound is recrystallized from chloroform.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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